Going from 1+1=2 to Quantum Mechanics Chaimongkol, 2026 We are going to look at a problem
V ( x ) = { 0 − a ≤ x ≤ a V 0 otherwise V(x) = \begin{cases} 0 & -a \leq x \leq a \\ V_0 & \text{otherwise} \end{cases} V ( x ) = { 0 V 0 − a ≤ x ≤ a otherwise
Describe the J ( x ) J(x) J ( x ) of the particle in all states
Note that in this case, we look at the bound state. Scattering is not useful. Reflecting state assumes V L ≠ V R V_L\neq V_R V L = V R which is not possible therefore it DNE.
The potential is even V ( − x ) = V ( x ) V(-x)=V(x) V ( − x ) = V ( x ) . A theorem says the bound eigenstates can be chosen such that ϕ ( x ) \phi(x) ϕ ( x ) is either even or odd.
Bound State, Even Wave function Case
ϕ ( x ) = { A e b x x < − a B cos ( k x ) − a ≤ x ≤ a A e − b x x > a \phi(x) = \begin{cases} Ae^{bx} & x < -a \\ B\cos(kx) & -a \leq x \leq a \\ Ae^{-bx} & x > a \end{cases} ϕ ( x ) = ⎩ ⎨ ⎧ A e b x B cos ( k x ) A e − b x x < − a − a ≤ x ≤ a x > a
where
k = 2 m E ℏ 2 , b = 2 m ( V 0 − E ) ℏ 2 k = \sqrt{\frac{2mE}{\hbar^2}}, \qquad b = \sqrt{\frac{2m(V_0 - E)}{\hbar^2}} k = ℏ 2 2 m E , b = ℏ 2 2 m ( V 0 − E )
Matching x = a x=a x = a
A e − b a = B cos ( k a ) (1) Ae^{-ba} = B\cos(ka) \tag{1} A e − ba = B cos ( k a ) ( 1 )
d d x ( A e − b x ) ∣ a = − b A e − b a \frac{d}{dx}\left(Ae^{-bx}\right)\Big|_{a} = -bAe^{-ba} d x d ( A e − b x ) a = − b A e − ba
d d x ( B cos ( k x ) ) ∣ a = − k B sin ( k a ) \frac{d}{dx}\left(B\cos(kx)\right)\Big|_{a} = -kB\sin(ka) d x d ( B cos ( k x ) ) a = − k B sin ( k a )
− b A e − b a = − k B sin ( k a ) (2) -bAe^{-ba} = -kB\sin(ka) \tag{2} − b A e − ba = − k B sin ( k a ) ( 2 )
Div (2) by (1)
− b A e − b a A e − b a = − k B sin ( k a ) B cos ( k a ) \frac{-bAe^{-ba}}{Ae^{-ba}} = \frac{-kB\sin(ka)}{B\cos(ka)} A e − ba − b A e − ba = B cos ( k a ) − k B sin ( k a )
− b = − k tan ( k a ) -b = -k\tan(ka) − b = − k tan ( k a )
b = k tan ( k a ) b = k\tan(ka) b = k tan ( k a )
This is transcendental -- you cannot isolate E E E algebraically. You must numerically solve this.
Let
z = k a , z 0 = 2 m V 0 ℏ 2 a z = ka, \qquad z_0 = \sqrt{\frac{2mV_0}{\hbar^2}}\,a z = k a , z 0 = ℏ 2 2 m V 0 a
where z z z is dimensionless inside wavenumber.
( b a ) 2 = 2 m ( V 0 − E ) ℏ 2 a 2 = 2 m V 0 ℏ 2 a 2 ⏟ z 0 2 − 2 m E ℏ 2 a 2 ⏟ z 2 = z 0 2 − z 2 (ba)^2 = \frac{2m(V_0 - E)}{\hbar^2}\,a^2 = \underbrace{\frac{2mV_0}{\hbar^2}a^2}_{z_0^2} - \underbrace{\frac{2mE}{\hbar^2}a^2}_{z^2} = z_0^2 - z^2 ( ba ) 2 = ℏ 2 2 m ( V 0 − E ) a 2 = z 0 2 ℏ 2 2 m V 0 a 2 − z 2 ℏ 2 2 m E a 2 = z 0 2 − z 2
so
b a = z 0 2 − z 2 ba=\sqrt{z_0^2-z^2} ba = z 0 2 − z 2
k 2 + b 2 = 2 m V 0 / ℏ 2 k^2+b^2=2mV_0/\hbar^2 k 2 + b 2 = 2 m V 0 / ℏ 2
so its a circle radius z 0 z_0 z 0 inside ( z , b a ) (z,ba) ( z , ba ) plane i.e., b a ba ba is on vertical axis and z z z is on horizontal axis
Bound State, Odd Wave function Case
ϕ ( x ) = { − A e b x x < − a B sin ( k x ) − a ≤ x ≤ a A e − b x x > a \phi(x) = \begin{cases} -Ae^{bx} & x < -a \\ B\sin(kx) & -a \leq x \leq a \\ Ae^{-bx} & x > a \end{cases} ϕ ( x ) = ⎩ ⎨ ⎧ − A e b x B sin ( k x ) A e − b x x < − a − a ≤ x ≤ a x > a
Odd parity
A e − b a = B sin ( k a ) (1) Ae^{-ba} = B\sin(ka) \tag{1} A e − ba = B sin ( k a ) ( 1 )
− b A e − b a = k B cos ( k a ) (2) -bAe^{-ba} = kB\cos(ka) \tag{2} − b A e − ba = k B cos ( k a ) ( 2 )
Div (2) by (1)
− b = k cot ( k a ) ⇒ b = − k cot ( k a ) -b = k\cot(ka) \;\Rightarrow\; b = -k\cot(ka) − b = k cot ( k a ) ⇒ b = − k cot ( k a )
Conclusion
This is the result
( z 0 z ) 2 − 1 = { tan z (even ϕ ) − cot z (odd ϕ ) \boxed{\sqrt{\left(\frac{z_0}{z}\right)^2 - 1} = \begin{cases} \tan z & \text{(even } \phi) \\ -\cot z & \text{(odd } \phi) \end{cases}} ( z z 0 ) 2 − 1 = { tan z − cot z (even ϕ ) (odd ϕ )
Bound State Solutions
If
n π 2 ≤ z 0 ≤ ( n + 1 ) π 2 \frac{n\pi}{2} \leq z_0 \leq \frac{(n+1)\pi}{2} 2 nπ ≤ z 0 ≤ 2 ( n + 1 ) π
Then n + 1 n+1 n + 1 bound states
Probability Current Problem 4